Two of country music's all-time greats come together to perform many of their classic hits, captured in the earliest days of their careers through vintage television appearances showcasing the artists at the peak of their fame. The colorful crooner Webb Pierce performs songs such as "Walking The Dog" and "There Stands The Glass" while guitar virtuoso Chet Atkins Performs picks on hits such as "Frankie & Johnny" and "Mr. Sandman."